U. Hohm et U. Trumper, RELATIVE DISPERSION OF THE 2ND REFRACTIVITY VIRIAL-COEFFICIENT OF XENON BETWEEN 633 NM AND 325 NM MEASURED FOR TEMPERATURES UP TO 1100 K, Molecular physics, 89(4), 1996, pp. 943-951
We report measurements of the difference of the reduced second refract
ivity virial coefficient Delta B(T) = B-R(325.13 nm, T)/A(R)(325.13 n
n, T)-B-R(632 99 nm, T)/A(R)(632.99 nm, T) of xenon in the temperature
range between 295 g and 1100 K. A(R)(lambda, T) and B-R(lambda, T) ar
e the first and second refractivity virial coefficients measured at la
mbda = 325.13 nm and lambda = 632.99 MI respectively. Delta B(T) is f
ound to decrease with increasing temperature T as 10(7) Delta B(T)/m(
3) mol(-1) = 12.6(6.8)xexp[-0.0038(13)x(T/K)] with a standard deviatio
n of 0.94x10(-7) m(3) mol(-1). With the aid of one absolute value of B
-R(lambda, T) and calculations based on an extended dipole-induced-dip
ole model, a normal dispersion of B-R(lambda, T) is found throughout t
he whole temperature range. This result is contrary to former room-tem
perature measurements, where an anomalous dispersion of B-R(lambda, T)
of xenon has been reported.