P. Schlottmann, INFLUENCE OF A KONDO-HOLE IMPURITY BAND ON MAGNETIC INSTABILITIES IN KONDO INSULATORS, Physical review. B, Condensed matter, 54(17), 1996, pp. 12324-12331
Kondo insulators like Ce3Bi4Pt3 and CeNiSn are compounds with small-ga
p semiconductor properties. The Kondo insulator is described by the no
ndegenerate symmetric Anderson lattice with, on average, two electrons
per site within Kotliar and Ruckenstein's mean-field approximation in
terms of four slave bosons per site. A Kondo hole is the charge neutr
al substitution of a rare earth or actinide atom by a nonmagnetic anal
og. An isolated Kondo hole gives rise to a bound state in the gap, whi
ch pins the Fermi level and has magnetic properties. A finite concentr
ation of Kondo holes generates an impurity band in the gap of the semi
conductor. The low-temperature thermodynamic and transport properties
are determined by the impunity band. The interplay of the f-electron c
orrelations with the impurity band is studied in the paramagnetic phas
e. On a bipartite lattice the pure Kondo insulator is unstable to long
-range antiferromagnetism for U > U-c acid to ferromagnetism in suffic
iently large magnetic fields. A small concentration of Kondo holes red
uces the threshold for the antiferromagnetic transition, giving rise t
o reentrance, but does not substantially affect ferromagnetism.