CHIROPTICAL LANTHANIDE(III) SCHIFF-BASE COMPLEXES DERIVED FROM D-CAMPHOR-BETA-SULFONIC ACID

Citation
Hz. Ma et al., CHIROPTICAL LANTHANIDE(III) SCHIFF-BASE COMPLEXES DERIVED FROM D-CAMPHOR-BETA-SULFONIC ACID, Polyhedron, 16(3), 1997, pp. 535-539
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
ISSN journal
02775387
Volume
16
Issue
3
Year of publication
1997
Pages
535 - 539
Database
ISI
SICI code
0277-5387(1997)16:3<535:CLSCDF>2.0.ZU;2-T
Abstract
The new chiral complexes of optical Schiff base ligand (NaHL) derived from D-camphor-beta-sulfonic acid and o-aminopherol with La-III, Pr-II I, Nd-III; Sm-III, Eu-III, Gd-III, Tb-III, Dy-III, Ho-III and Er-III h ave been synthesized and characterized by elemental analysis, molar co nductance, XPS, fluorescence, IR, electronic spectra and magnetic susc eptibility measurements and thermal (TG,DTA,DTG) methods. Their domina nt conformers were determined from CD spectra and support by H-1 NMR d ata. Copyright (C) 1996 Elsevier Science Ltd