SYNTHESIS AND STRUCTURES OF NOVEL OCTADECANUCLEAR CLUSTERS H)(24)(PYB)(12)(H2O)(18)(MU(12)-CLO4)](17+)(RE=SM, EU)

Authors
CHEN XM WU YL WANG RJ
Citation
Xm. Chen et al., SYNTHESIS AND STRUCTURES OF NOVEL OCTADECANUCLEAR CLUSTERS H)(24)(PYB)(12)(H2O)(18)(MU(12)-CLO4)](17+)(RE=SM, EU), Science in China. Series B, Chemistry, life sciences & earth sciences, 39(5), 1996, pp. 536-545
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Science in China. Series B, Chemistry, life sciences & earth sciences → ACNP
ISSN journal
1001652X
Volume
39
Issue
5
Year of publication
1996
Pages
536 - 545
Database
ISI
SICI code
1001-652X(1996)39:5<536:SASONO>2.0.ZU;2-I
Abstract
The novel octadecanuclear Cu-RE duster have been isolated from the rea ction system of aqueous Cu2+-RE(3+)-pyb (RE=Sm, Eu; pyb=pyridine betai ne) and characterized by single-crystal structural analysis. The resul ts show that the clusters comprise a [Cu(12)RE(6) (mu(5)-OH)(24)(mu(12 )-ClO4)](17+) octahedral core, which encapsulates a ClO4- ion and has 18 water molecules and 12 bridging pyb carboxylato ligands as external ligands.