COMPUTATIONAL VIEW OF THE MECHANISM OF VINYLPHOSPHIRANE PYROLYSIS ANDA NEW ROUTE TO PHOSPHAALKYNES

Results obtained with semiempirical MO methods support a mechanism for the pyrolysis of vinylphosphirane yielding phosphapropyne in which ex trusion of ethylene leads to a vinylphosphinidene intermediate. A path way from vinylphosphinidene to phosphapropyne involving 2H-phosphirene and 2-phosphapropenylidene intermediates is predicted from high level ab initio results to have a higher energy barrier than that for direc t rearrangement; A higher energy pathway ii om vinylphosphirane is the migration of a hydrogen atom forming methyl(1-phosphiranyl)methylene, followed by loss of ethylene to yield the phosphaalkyne product. Howe ver, since fragmentation of 1-phosphiranylmethylene, once formed, has a low predicted barrier, its generation emerged as a new route to phos phaalkynes. (Trimethylsilyl)-(1-phosphiranyl)diazomethane was synthesi zed, and its pyrolysis yields Me(3)SiC=P.