Yt. Liu et al., AN OPTIMIZED 2ND-ORDER PERTURBATIVE STUDY OF THE ASYMMETRICAL QUANTUMANHARMONIC-OSCILLATOR, Nuovo cimento della Societa italiana di fisica. B, Relativity, classical and statistical physics, 111(10), 1996, pp. 1235-1245
We study the energy eigenvalues of a cubic-quartic anharmonic oscillat
or with the operator method introduced by Feranchuk and Komarov (Ann.
Phys. (N.Y.), 238 (1995) 370). Based on the minimization of the second
-order perturbative correction and the energy-variance, a simple optim
ized second-order perturbative calculation is found to yield very accu
rate energies especially for the excited states: the asymptotic error
is shown to be - 0.002 %. When the same method is applied to an oscill
ator with the sextic anharmonic potential x(2)/2 (j=3)Sigma(6) x(j), s
imilar accuracy is obtained for the excited states with an asymptotic
error of about -0.003 %.