N. Yamazoe et al., ROLE OF HETERO-JUNCTIONS IN OXIDE SEMICONDUCTOR GAS SENSORS, Materials science & engineering. B, Solid-state materials for advanced technology, 41(1), 1996, pp. 178-181
A new design concept of semiconductor gas sensors, which introduces a
foreign antenna material to a gas in problem, is described for the det
ection of dilute odorous gases such as HN3 and H2S. The antenna materi
al, dispersed on the surface of a semiconducting oxide, interacts with
the gas sensitively and selectively, and the resulting change in its
chemical stale induces a change in semiconducting properties of the un
derlying oxide through hetero-junctions. Typical examples of such sens
ors include NH3 sensors using Au- and Pt-WO3 and an H2S sensor using C
uO-SnO2.