Local mass transfer studies have been carried out in an external loop
airlift reactor and indicated the existence of significant non-uniform
ities in aeration capacity in the various sections of the reactor. The
traditional assumption of a single well mixed unit with a single k(L)
a value for external loop airlift reactors was found to be poor and c
annot represent adequately the reactor as a whole. The liquid head in
the gas/liquid separator was found to have a significant negative effe
ct on the local mass transfer coefficient k(L) a. Visualization of flo
w patterns showed the existence of strong vortices in the riser and do
wncomer which contributed to a reduction in local aeration capacity. M
ass transfer experiments in an aerated tank showed that the aeration c
apacity can be reduced by half in viscous media but improved significa
ntly in the presence of salts.