Kc. Link et Eu. Schlunder, A NEW METHOD FOR THE CHARACTERIZATION OF THE WETTABILITY OF POWDERS, Chemical engineering & technology, 19(5), 1996, pp. 432-437
The wetting characteristics of fine powders play an important role in
a variety of processes. The most important way of characterising the w
ettability of a fluid/fluid/solid system is to measure the contact ang
le. This paper describes a relatively simple method for the determinat
ion of the contact angle on powdery materials. The technique involves
the measurement of the dynamic contact angle which is formed when a li
quid drop is placed on a horizontal porous surface. On the basis of th
e measured dynamic contact angle as a function of time an ''apparent''
static contact angle has been defined, which gives a measure of the w
ettability of porous solid systems by analogy with the wetting of non-
porous solids. Determinations with glass beads and NaCl-powders as the
test materials indicate that the measured value depends on the partic
le size of the powder, the porosity and the temperature. It was conclu
ded that the capillary penetration of the liquid droplet into the poro
us media itself influences the wetting characteristics.