SYNTHESIS IN SOLID-STATE, STRUCTURAL REGULARITY AND REACTION-MECHANISM FOR [VS4-CU-N] CLUSTERS

Authors
YU XF ZHENG FK HUANG JS
Citation
Xf. Yu et al., SYNTHESIS IN SOLID-STATE, STRUCTURAL REGULARITY AND REACTION-MECHANISM FOR [VS4-CU-N] CLUSTERS, Science in China. Series B, Chemistry, life sciences & earth sciences, 39(4), 1996, pp. 433-438
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Science in China. Series B, Chemistry, life sciences & earth sciences → ACNP
ISSN journal
1001652X
Volume
39
Issue
4
Year of publication
1996
Pages
433 - 438
Database
ISI
SICI code
1001-652X(1996)39:4<433:SISSRA>2.0.ZU;2-P
Abstract
The reaction system (NH4)(3)VS4/CuCl/PPh(3)/Et(4)NBr afforded a series of [VS4-Cu-n] clusters with various core configurations in the solid state at low heating temperature. The structural regularity of [VS4-Cu -n] clusters and the influence of the CuCL:(NH4)(3)VS4 ratio as well a s that of reaction temperature and time on the formation of cluster co re have been summarized. The reaction mechanism of forming V-Cu-S clus ters has also been explored.