ULTRAFILTRATION OF MICELLAR SOLUTIONS IN THE PRESENCE OF ELECTROLYTES

Micellar extraction coupled with ultrafiltration techniques represents a potentially attractive tool for the removal of different kinds of c ontaminants from waste waters. Even though most industrial streams to be treated contain large amounts of electrolytes, very little is known about the behavior of micellar solutions in ultrafiltration when larg e amounts of salts are present. This paper is concerned with an invest igation of two cationic surfactants (cetyltrimethylammonium bromide (C TAB) and cetylpyridinium chloride (CPC)) and one anionic surfactant (s odium dodecylsulfate (SDS)) in the presence of several salts occurring in specific industrial processes (carbonates and hydrogenocarbonates, nitrites, nitrates). The ultrafiltration behavior of these systems, w ith individual salt concentrations up to 0.9 M, is studied from the vi ewpoint of the fluxes obtained, the amount of surfactant leakage and o f the membrane ''gel point.'' Two types of polymeric membranes with mo lecular weight cutoff of 10,000 Da are considered (cellulose and polys ulfone), which show significantly different behaviors. (C) 1996 Academ ic Press, Inc.