DRAGOS E-PARAMETER, C-PARAMETER AND T-PARAMETER FOR SOME MONOVALENT-METAL AND BIVALENT-METAL IONS - LACK OF CORRESPONDENCE WITH PEARSONS CHEMICAL HARDNESS
S. Hati et D. Datta, DRAGOS E-PARAMETER, C-PARAMETER AND T-PARAMETER FOR SOME MONOVALENT-METAL AND BIVALENT-METAL IONS - LACK OF CORRESPONDENCE WITH PEARSONS CHEMICAL HARDNESS, Proceedings of the Indian Academy of Sciences. Chemical sciences, 108(5), 1996, pp. 445-449
Drago's e, c and t parameters for a number of chemically important mon
o- and bivalent metal ions are estimated from the heterolytic bond dis
sociation energy data of their binary halides, hydrides and methides.
An important result is that, for the cationic acids, the c and t param
eters are not two independent variables. Attempts to correlate these p
arameters or any combination of these with Pearson's chemical hardness
have been unsuccessful so far.