KINETICS OF ALKALINE-HYDROLYSIS OF 2-ETHYLBUTYLFORMATE

Citation
B. Chaudhuri et al., KINETICS OF ALKALINE-HYDROLYSIS OF 2-ETHYLBUTYLFORMATE, Canadian journal of chemical engineering, 74(5), 1996, pp. 806-810
Citations number
7
Categorie Soggetti
Engineering, Chemical
ISSN journal
00084034
Volume
74
Issue
5
Year of publication
1996
Pages
806 - 810
Database
ISI
SICI code
0008-4034(1996)74:5<806:KOAO2>2.0.ZU;2-S
Abstract
The theory of mass transfer accompanied by chemical reaction has been used for studying the kinetics of alkaline hydrolysis of 2-ethylbutylf ormate at different temperatures and ionic strengths of aqueous alkali ne solution. Experiments have been conducted in a stirred cell having a flat liquid-liquid interface. For aqueous phases containing 1-3 kmol /m(3) sodium hydroxide, the alkaline hydrolysis conforms to the fast p seudo-first order reaction regime. The system is of considerable pract ical importance and can be successfully employed for the measurement o f the interfacial area of a mechanically-agitated and flooded packed-b ed liquid-liquid contactor.