THERMOCHEMISTRY OF ADDUCTS OF ARSENIC TRIHALIDES WITH SATURATED HETEROCYCLIC BASES

Authors
DUNSTAN PO
Citation
Po. Dunstan, THERMOCHEMISTRY OF ADDUCTS OF ARSENIC TRIHALIDES WITH SATURATED HETEROCYCLIC BASES, Journal of chemical and engineering data, 41(6), 1996, pp. 1450-1454
Citations number
22
Categorie Soggetti
Engineering, Chemical",Chemistry
Journal title
Journal of chemical and engineering data → ACNP
ISSN journal
00219568
Volume
41
Issue
6
Year of publication
1996
Pages
1450 - 1454
Database
ISI
SICI code
0021-9568(1996)41:6<1450:TOAOAT>2.0.ZU;2-0
Abstract
The adducts AsX(3) . nL (where L is piperazine (Pipz), morpholine (Mor ph), or piperidine (Pipd); X is Cl, Br, or I; and n is 1, 3/2, or 2) h ave been synthesized and characterized by melting points, elemental an alysis, thermal studies, and infrared spectroscopy. By means of calori metric measurements in solution, the mean standard enthalpies of the a rsenic-nitrogen bonds were determined as well as the values of other t hermochemical parameters of the adducts.