IONIC ASSOCIATION AND CONDUCTANCES OF SOME SYMMETRICAL TETRAALKYLAMMONIUM PERCHLORATES IN 2-METHOXYETHANOL PLUS WATER AT 298.15 K

Authors
DAS B HAZRA DK
Citation
B. Das et Dk. Hazra, IONIC ASSOCIATION AND CONDUCTANCES OF SOME SYMMETRICAL TETRAALKYLAMMONIUM PERCHLORATES IN 2-METHOXYETHANOL PLUS WATER AT 298.15 K, Journal of chemical and engineering data, 41(6), 1996, pp. 1470-1472
Citations number
18
Categorie Soggetti
Engineering, Chemical",Chemistry
Journal title
Journal of chemical and engineering data → ACNP
ISSN journal
00219568
Volume
41
Issue
6
Year of publication
1996
Pages
1470 - 1472
Database
ISI
SICI code
0021-9568(1996)41:6<1470:IAACOS>2.0.ZU;2-Z
Abstract
Precise conductance measurements are reported for tetraethylammonium p erchlorate (Et(4)NClO(4)), tetrapropylammonium perchlorate (Pr4NClO4), and tetrabutylammonium perchlorate (Bu(4)NClO(4)) in 2-methoxyethanol (1) + water (2) at 298.15 K. The limiting molar conductivity (Lambda degrees), the association constant (K-A), and the association distance (R) in the solvent mixtures have been evaluated from the conductance- concentration data using the 1978 Fuoss conductance equation. The resu lts have been explained in terms of ion-ion interactions and the struc tural changes in the solvent mixtures.