Je. Ramirez et al., DUAL PRECIPITATION STRENGTHENING EFFECT OF COPPER AND NIOBIUM IN HIGH-STRENGTH STEEL WELD METAL, Materials science & engineering. A, Structural materials: properties, microstructure and processing, 216(1-2), 1996, pp. 91-103
Experimental work to produce high strength steel welds with systematic
additions of copper (up to 3.5 wt.pct.) and niobium (up to 0.45 wt.pc
t.) at 3.6 kJ mm(-1) (90 kJ in(-1)) heat input was carried out. Copper
additions were found to precipitation strengthen the high strength st
eel weld metals. An estimated yield strength of 900 MPa (130 ksi) can
be achieved in single-pass welds with approximately 2.8 wt.pct. of cop
per addition. Nevertheless, multipass welding over the copper-enhanced
weld deposit resulted in nonuniform weld metal properties across the
weld beads. Niobium additions did not provide as powerful a strengthen
ing effect in the single-pass high heat input welds as the copper addi
tions. At approximately 3.2 wt.pct. copper and 0.06 wt.pct. niobium in
the weld deposits, the two elements provided the required strengtheni
ng effect with thermally stable precipitates to produce high strength
steel weld metals that exhibited acceptable properties in high heat in
put, single- and multi-pass conditions. The combined effect of copper
and niobium in high strength steel weld metal derives from the combina
tion of two kinds of precipitates with distinct precipitation reaction
kinetics and thermal stability.