OXIDATION BEHAVIOR OF EQUIATOMIC TINI ALLOY IN HIGH-TEMPERATURE AIR ENVIRONMENT

The isothermal oxidation behavior of equiatomic TiNi shape memory allo y in dry air from 550 to 1000 degrees C is studied with thermogravimet ric analysis. The alloy's scale layer is further investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and electron pr obe microanalyzer. Experimental results indicate that a multi-layered scale is formed, consisting of an outer rutile layer, a porous interme diate layer of mixture of TiO2 and Ni(Ti), and a thin inner TiNi3 laye r. The intermediate layer, furthermore, exhibits a stripe-like lamella r structure at the TiNi3 interface. The apparent activation energy of TiNi alloy oxidation is 226 kJ/mol, and the oxidation rate follows a p arabolic law. A schematic oxidation mechanism of TiNi alloy is propose d to explain the observed results.