INTRINSIC PROTON AFFINITY OF REACTIVE SURFACE GROUPS OF METAL (HYDR)OXIDES - THE BOND VALENCE PRINCIPLE

The proton affinity of individual surface groups has been calculated w ith a redefined version of the multi site complexation (MUSIC) model. In the new approach the proton affinity of an oxygen originates from t he undersaturation of the oxygen valence. The factors valence and coor dination number, which are the basis of Pauling's definition of bond v alence, in combination with the number of coordinating (Me and H) ions , are dominant in determining the proton affinity. The neutralization of an oxygen by Me ion(s) is calculated on the basis of the actual bon d valence, which accounts for structural details, resulting from an as ymmetrical distribution of charge in the coordination environment. An important role in the new version of the MUSIC model is given to the H bonds. The model shows that the proton affinity is determined not onl y by the number of donating H bonds but also by the number of acceptin g H bonds. The proton affinity of surface groups and of solution compl exes can be understood in one theoretical framework, on the basis of a different number of donating and accepting H bonds. The MUSIC model p redicts tile variation in proton affinity constants fur surface groups in particular those with the same number of coordinating Me ions but with a different structural position. The model is able to predict on the basis of the proton affinity of the individual groups the correct PZC of Me hydroxides, oxohydroxides, and oxides, and explains previous exceptions. The model san also be applied in general to other mineral s. (C) 1996, Academic Press, Inc.