EDWARD-WILKINSON BEHAVIOR OF CRYSTAL-SURFACES GROWN BY SEDIMENTATION OF SIO2 NANOSPHERES

The surface of the solid structures obtained by natural sedimentation from aqueous solutions of monodisperse SiO2 spheres is imaged by atomi c force microscopy. The dynamic scaling method applied to these images leads to temporal and spatial logarithmic scalings of the surface wid th that is consistent with the Edward-Wilkinson interface motion equat ion. It suggests that the interface grows close to equilibrium by the aggregation of SiO2 spheres which, after reaching the growing surface driven by gravity, relax to minimum potential energy sites without sig nificant attractive particle-particle interactions.