SYNTHESIS OF NEW ZIRCONIUM-CONTAINING POL YMERS

Authors
PLATONOVA OA SEREGINA MV BRONSHTEIN LM VALETSKII PM EZERNITSKAYA MG YANOVSKAYA IM VYGODSKII YS BRANDUKOVA NE
Citation
Oa. Platonova et al., SYNTHESIS OF NEW ZIRCONIUM-CONTAINING POL YMERS, Vysokomolekularnye soedinenia. Seria A, 38(9), 1996, pp. 1619-1622
Citations number
11
Categorie Soggetti
Polymer Sciences
Journal title
Vysokomolekularnye soedinenia. Seria A → ACNP
ISSN journal
05075475
Volume
38
Issue
9
Year of publication
1996
Pages
1619 - 1622
Database
ISI
SICI code
0507-5475(1996)38:9<1619:SONZPY>2.0.ZU;2-I
Abstract
Reaction of zirconocene dichloride Cp(2)ZrCl(2) with aromatic polymers hearing alpha-diketone and alpha-hydroxyketone fragments was studied. Using reactions of Cp(2)ZrCl(2) with benzil and benzoin, which model alpha-diketone and alpha-hydroxyketone fragments, it was shown that zi rconocene dichloride reacts only with hydroxyketone groups of the poly mer through both reaction with OH group and coordination of Zn to the keto group. The prepared polymers are rather stable and can show promi se as catalysts for a number of organic reactions.