The dust emission spectrum between 5 and 16 mu m has been measured at
the northern edge of the dense cloud in Ophiuchus at a position where
the radiation field intensity is estimated to be 10-20 times the mean
Solar neighborhood value. The spectrum shows the well known emission b
ands at 6.2, 7.7, 8.6, 11.3 and 12.7 mu m. ISO allows to detect the em
ission features for a radiation field intensity two orders of magnitud
e smaller than in the objects previously observed. Since all of these
bands are considered to be characteristic of C-C or C-H bonds in aroma
tic hydrocarbons this observation strongly supports the existence of l
arge aromatic molecules in the general interstellar medium. An importa
nt result of the observation is the presence of a significant continuu
m below the features at all wavelengths, and in particular, a featurel
ess continuum between the 8.6 and 11.3 mu m features and beyond that a
t 12.7 mu m. The Ophiuchus spectrum is remarkably similar to that meas
ured in NGC 7023. We argue that both the bands and the continuum emiss
ion must come from molecules or small aggregates with less than a few
hundred carbon atoms.