AGGREGATIVE ACTIVATION AND CARBANION CHEMISTRY - COMPLEX BASE DEPROTONATION AND DIRECTED FUNCTIONALIZATION OF DITHIOACETALS

Authors
GROS P HANSEN P CAUBERE P
Citation
P. Gros et al., AGGREGATIVE ACTIVATION AND CARBANION CHEMISTRY - COMPLEX BASE DEPROTONATION AND DIRECTED FUNCTIONALIZATION OF DITHIOACETALS, Tetrahedron, 52(48), 1996, pp. 15147-15156
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
48
Year of publication
1996
Pages
15147 - 15156
Database
ISI
SICI code
0040-4020(1996)52:48<15147:AAACC->2.0.ZU;2-P
Abstract
Bis(phenylthio)methane and [1,3]-dithiane were efficiently deprotonate d by the NaNH2-Et(OCH2CH2)(2)-ONa complex base. A marked behaviour dif ference was observed between the sodium carbanion of [1,3]-dithiane an d the corresponding lithio-derivative; A ''radicaioid'' mechanism is p roposed to explain the results observed. Copyright (C) 1996 Elsevier S cience Ltd