QUADRUPOLAR [1(4)] (META-ORTHO)(2) AZOLOPHANES - INTRAMOLECULAR C-H-CENTER-DOT-CENTER-DOT-CENTER-DOT-N AND TO WATER C-H-CENTER-DOT-CENTER-DOT-CENTER-DOT-O HYDROGEN-BONDING REVEALED BY X-RAY-DIFFRACTION

Authors
ALCADE E GISBERT M ALVAREZRUA C GARCIAGRANDA S
Citation
E. Alcade et al., QUADRUPOLAR [1(4)] (META-ORTHO)(2) AZOLOPHANES - INTRAMOLECULAR C-H-CENTER-DOT-CENTER-DOT-CENTER-DOT-N AND TO WATER C-H-CENTER-DOT-CENTER-DOT-CENTER-DOT-O HYDROGEN-BONDING REVEALED BY X-RAY-DIFFRACTION, Tetrahedron, 52(48), 1996, pp. 15189-15196
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
48
Year of publication
1996
Pages
15189 - 15196
Database
ISI
SICI code
0040-4020(1996)52:48<15189:Q[(A-I>2.0.ZU;2-Z
Abstract
The first X-ray crystallographic diffraction of an example of the titl e heterophanes built up from heterocyclic betaine subunits is reported and its quadrupolar character is confirmed. The crystal packing of 2 . 4H(2)O is mainly governed by hydrogen-bonding networks, strong inter molecular interactions with water together with weak interactions, eit her intramolecular or with water. Copyright (C) 1996 Elsevier Science Ltd