Positron annihilation spectra of arsenic- and gold-implanted silicon a
re compared:with spectra from bulk samples of arsenic and gold. Spectr
a with strongly reduced background intensities were recorded using a t
wo detector coincidence system with a variable-energy positron beam. I
t is shown that features in the high-momentum region of the spectra (s
imilar to 514-520 keV) can be identified with particular elements and
that this identification is independent of structure, i.e., whether th
e element forms the bulk or is an implanted impurity. Proportionality
between the intensity of characteristic spectral features and the frac
tion of annihilating positrons is also demonstrated, using the native
oxide on a silicon wafer as a test case. (C) 1996 American Institute o
f Physics.