NICKEL-CATALYZED COUPLING REACTION OF LITHIUM ORGANOBORATES AND ARYL MESYLATES POSSESSING AN ELECTRON-WITHDRAWING GROUP

Authors
KOBAYASHI Y MIZOJIRI R
Citation
Y. Kobayashi et R. Mizojiri, NICKEL-CATALYZED COUPLING REACTION OF LITHIUM ORGANOBORATES AND ARYL MESYLATES POSSESSING AN ELECTRON-WITHDRAWING GROUP, Tetrahedron letters, 37(47), 1996, pp. 8531-8534
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
47
Year of publication
1996
Pages
8531 - 8534
Database
ISI
SICI code
0040-4039(1996)37:47<8531:NCROLO>2.0.ZU;2-D
Abstract
In the presence of NiCl2(PPh(3))(2) as catalyst, p-methoxycarbonylphen y mesylate (5) and tosylate (6) react with lithium arylborates 4 (Ar = 2-furyl; Ph, p-Me-Ph, p-MeO-Ph) at room temperature to afford the cou pling products in high yields. Similarly. mesylates 9-11 coupled with these berates 4 efficiently. Copyright (C) 1996 Elsevier Science Ltd