NONENZYMATIC ENANTIOSELECTIVE ACYLATION OF RACEMIC SECONDARY ALCOHOLSCATALYZED BY A SNX(2)-CHIRAL DIAMINE COMPLEX

Authors
ORIYAMA T HORI Y IMAI K SASAKI R
Citation
T. Oriyama et al., NONENZYMATIC ENANTIOSELECTIVE ACYLATION OF RACEMIC SECONDARY ALCOHOLSCATALYZED BY A SNX(2)-CHIRAL DIAMINE COMPLEX, Tetrahedron letters, 37(47), 1996, pp. 8543-8546
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
47
Year of publication
1996
Pages
8543 - 8546
Database
ISI
SICI code
0040-4039(1996)37:47<8543:NEAORS>2.0.ZU;2-1
Abstract
Kinetic resolution of racemic secondary alcohols has been achieved by the reaction with benzoyl halide in the presence of a SnX(2)-chiral di amine complex to afford the corresponding benzoate in good to excellen t enantioselectivities. Copyright (C) 1996 Elsevier Science Ltd