SUZUKI-COUPLING OF CP-ASTERISK-RU(PARA-C6H4BR2) WITH PHENYL BORONIC ACID - A MODEL REACTION FOR THE SYNTHESIS OF ORGANOMETALLIC POLYMERS

Authors
HARRE K ENKELMANN V SCHULZE M BUNZ UHF
Citation
K. Harre et al., SUZUKI-COUPLING OF CP-ASTERISK-RU(PARA-C6H4BR2) WITH PHENYL BORONIC ACID - A MODEL REACTION FOR THE SYNTHESIS OF ORGANOMETALLIC POLYMERS, Chemische Berichte, 129(11), 1996, pp. 1323-1325
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Chemische Berichte → ACNP
ISSN journal
00092940
Volume
129
Issue
11
Year of publication
1996
Pages
1323 - 1325
Database
ISI
SICI code
0009-2940(1996)129:11<1323:SOCWPB>2.0.ZU;2-A
Abstract
The synthesis of a terphenyl derivative complexed by the cationic moie ty CpRu+ by Suzuki coupling of [Cp*Ru(BrC6H4-Br)]OTf with phenyl boro nic acid under catalysis of Pd(PP3)(4) in a DME-water mixture at 85 de grees C in quantitative yield is reported. The stable coupling product 3 was characterized by X-ray crystal structure analysis.