We examine the density-dependent metal-nonmetal transition (MNMT) for
the Group 1 elements hydrogen, rubidium and caesium. Remarkably, the e
xperimentally observed metallization densities agree closely with thos
e predicted from the 1927 classical theory of K. F. Herzfeld, which ou
tlines the critical conditions necessary for the metallization of any
element of the periodic system. The metallization densities of the alk
ali metal elements are also consistent with the quantum mechanical the
ory of the MNMT, as first set out by Sir Nevill Mott.