MOLECULAR ADDUCTS OF DIORGANOTIN DICHLORIDE WITH N-(2-OXIDOARYLIDENEAMINOACIDATO) DIORGANOTIN(IV) COMPLEXES - CRYSTAL-STRUCTURE OF [PH(2)SN(2-OC10H6CH=NCH2COO)]SNPH(2)CL(2)

Authors
KHOO LE XU Y GOH NK CHIA LS KOH LL
Citation
Le. Khoo et al., MOLECULAR ADDUCTS OF DIORGANOTIN DICHLORIDE WITH N-(2-OXIDOARYLIDENEAMINOACIDATO) DIORGANOTIN(IV) COMPLEXES - CRYSTAL-STRUCTURE OF [PH(2)SN(2-OC10H6CH=NCH2COO)]SNPH(2)CL(2), Polyhedron, 16(4), 1997, pp. 573-576
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
4
Year of publication
1997
Pages
573 - 576
Database
ISI
SICI code
0277-5387(1997)16:4<573:MAODDW>2.0.ZU;2-S
Abstract
Three new dinuclear tin complexes, [Me(2)Sn(2-OC6H4CH=NCH{Pr-i}COO)]Sn Me(2)Cl(2) (1), [Me(2)Sn(2-OC10H6CH=NCH2COO)]SnMe(2)Cl(2) (2) and [Ph( 2)Sn(2-OC10H6CH=NCH2COO)]SnPh(2)Cl(2) (3), were prepared and character ized by spectroscopic studies and elemental analyses as a 1:1 adduct b etween diorganotin dichloride (acceptor) and bicycloazastannoxide (don or). A full X-ray crystal structure analysis was performed on 3 and th e results confirmed that the donor and the acceptor moieties of 3 are bonded with an Sn-O bond distance of 2.307 Angstrom. Copyright (C) 199 6 Elsevier Science Ltd