METAL SUBSTITUTION-REACTION IN THE CLUSTER (MU-H)(2)FE-3(MU(3)-SE)(CO)(9) .2. CRYSTAL AND MOLECULAR-STRUCTURE OF [FEW2(MU(3)-SE)(CO)(7)-CP(2)] AND [FEMOW(MU(3)-SE)(CO)(7)CP(2)] (CP=ETA(5)-C5H5)

Authors
KONCHENKO SN VIROVETS AV TKACHEV SV PODBEREZSKAYA NV
Citation
Sn. Konchenko et al., METAL SUBSTITUTION-REACTION IN THE CLUSTER (MU-H)(2)FE-3(MU(3)-SE)(CO)(9) .2. CRYSTAL AND MOLECULAR-STRUCTURE OF [FEW2(MU(3)-SE)(CO)(7)-CP(2)] AND [FEMOW(MU(3)-SE)(CO)(7)CP(2)] (CP=ETA(5)-C5H5), Polyhedron, 16(4), 1997, pp. 707-712
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
4
Year of publication
1997
Pages
707 - 712
Database
ISI
SICI code
0277-5387(1997)16:4<707:MSITC(>2.0.ZU;2-A
Abstract
The sequential substitution of two Fe(CO)(3) groups in [(mu-H)(2)Fe-3( mu(3)-Se) (CO)(9)] with isolobal fragments CpW(CO)(2) (the first stage ) and CpMo(CO), (the second stage) has been shown to result in the tit le heterotrimetal cluster [FeMoW(mu(3)-Se) (CO)(7)Cp(2)]. Its structur e and the structure of its [FeW2(mu(3)-Se)(CO)(7)Cp(2)] analog obtaine d previously have been determined by X-ray analysis. Copyright (C) 199 6 Elsevier Science Ltd