EFFECT OF THE MEDIUM ON THE MECHANICAL-PR OPERTIES OF CATALYSTS

Citation
Ed. Shchukin et al., EFFECT OF THE MEDIUM ON THE MECHANICAL-PR OPERTIES OF CATALYSTS, Uspehi himii, 65(9), 1996, pp. 881-891
Citations number
105
Categorie Soggetti
Chemistry
Journal title
ISSN journal
00421308
Volume
65
Issue
9
Year of publication
1996
Pages
881 - 891
Database
ISI
SICI code
0042-1308(1996)65:9<881:EOTMOT>2.0.ZU;2-#
Abstract
The phenomena of decreasing the catalyst's strength and durability und er working conditions have been considered. These phenomena have been treated as a manifestation of the media - catalyst interactions during catalytical process. The theoretical analysis of micromechanism and c ontrolling factors and conditions gives one to elaborate the methods o f essential enhancement of catalyst quality. The rate of surface self- diffusion is shown to be increased many times due to the appearance of a great amount of surface adatoms together with interatomic bonds rup ture. This effect permits to decrease the sintering temperature of pow der.