Representative volume (RV) of a composite material is important not on
ly for experimental determination of materials properties, but also fo
r theoretical analysis of various properties of the materials. RV is a
random variable; this is especially true for the composites with hete
rogeneous microstructures. In the present study, RV is redefined as a
relationship among three parameters: the volume under consideration, t
he measured or predicted value of a property corresponding to the volu
me, and the scattering of the property from the real effective propert
y. There are two steps involved to determine RV. The first is to deter
mine the relationship among the effective property, the properties of
each constituents, and volume fractions, which is the topic in composi
te mechanics. The second is determination of the local variation of th
e heterogeneity of the composite because, with increasing size of the
local volume, the statistics from the local volume asymptotically appr
oaches the value from the global average. The main purpose of this stu
dy is to develop a theoretical model to determine local variation of h
eterogeneity, which is obviously related to the morphological features
of the composites. The model accounts for coarseness of grain sizes,
volume fractions, spatial arrangement of the constituents, and propert
ies of each constituents. By combining the model with available compos
ite models for effective properties of composites, RV for various mate
rials properties can be developed. As an example, RV for elastic modul
i of cementitious materials is demonstrated.