CRITICAL ANALYSIS OF POTENTIOSTATIC STEP DATA FOR OXYGEN-TRANSPORT INELECTRONICALLY CONDUCTING PEROVSKITES

The solid-state potentiostatic technique is a convenient and versatile tool for studying oxygen transport in electronically conducting perov skites. Furthermore, a systematic analysis of the relaxation data help s elucidate the mechanistic nature of the prevalent oxygen rate proces s. As a case in point, we describe potential step measurements on 90% dense samples of SrCo1-xFexO3-delta, focusing per se on the assumption s underlying the technique and the interpretation of results. Careful analysis of the current-relaxation data pointed to the presence of hig h-diffusivity paths in the samples. It also indicated that the overall transport rate is controlled by an oxygen exchange reaction at the gr ain boundaries. This complication prevented unambiguous assessment of the chemical diffusion coefficient in this material. In addition, the analysis showed that wide disagreements in the oxygen chemical diffusi on coefficients reported in the literature for doped perovskites may b e attributed to differences in the sample quality (e.g., density, grai n size, and distribution) and the measurement technique employed.