The light-emitting porous silicon is treated by the rapid thermal proc
ess at 900-1100 degrees C under NH3 environment. The infrared absorpti
on spectra and Auger electron spectra show that the surface of porous
silicon is covered with a nitride-containing layer. From the electron
spin resonance, the density of dangling bonds is found to be quite low
. The photoluminescence intensity shows a slight decay under the laser
illumination and remains almost unchanged after three months storage
in the ambient air. All of these results illustrate that the nitride c
ould be an effective passivation film on the surface of porous silicon
. (C) 1996 American Institute of Physics.