ATMOSPHERIC SULFUR OVER THE EAST MEDITERRANEAN REGION

Particulate sulfate has been measured intermittently at various ground sites in Israel and from an instrumented aircraft for a 10- year peri od between 1984 and 1993. The measurements were accompanied by concurr ent monitoring of primary and secondary air pollutants and meteorologi cal parameters. In three studies, Etzion 1984-1986, Jerusalem 1987-198 8, and Jerusalem 1990-1991, measurements were taken for at least a yea r. The other studies were performed during summer months when higher l evels of secondary pollutants, including particulate sulfate, were obs erved. In most of the studies samples were taken for four sequential 6 -hour time segments. In one study, at Caesarea 1993, sulfate samples w ere taken only when wind flows were perpendicular to the coastline. Th e airborne measurements were performed along three north-south paths i nside the planetary boundary layer, over the Mediterranean coast, over the Judea-Samaria mountains and over the Jordan Valley. Each flight p ath consisted of 30 to 45 minutes of continuous sampling of SO2 and on e integrated sample of particulate sulfate. In all of our studies the concentration of particulate sulfate observed was relatively high comp ared with Other world locations. The highest values, occasionally exce eding 500 nmole m(-3) were found during the summer. Wintertime levels were in the range of 50-100 nmole m(-3). The annual average, calculate d for the three long studies, is 100 +/- 15 nmole m(-3), which is twic e as high as predicted for the region by a global model and as high as reported for some of the more polluted regions in the US. Several ind icators suggested that the origin of the sulfate in the region is not from local sources but the result of long range transport. The indicat ors include the lack of correlation between particulate sulfate and pr imary pollutants, the high sulfate to total sulfur values, the origin of the airmass back trajectories and the fact that similar levels were observed during concurrent periods at different sites. Throughout the study, higher concentration of particulate sulfate was found during t he afternoon hours, especially during the summer and at the inland loc ations. The contribution to the afternoon elevated values could not be associated with long range transport and results probably from major sulfur emission sources located along the Israeli Mediterranean coast.