CO5BP3O14 - THE FIRST BOROPHOSPHATE WITH PLANAR BO3 GROUPS CONNECTED TO PO4 TETRAHEDRA

Authors
BONTCHEV RP SEVOV SC
Citation
Rp. Bontchev et Sc. Sevov, CO5BP3O14 - THE FIRST BOROPHOSPHATE WITH PLANAR BO3 GROUPS CONNECTED TO PO4 TETRAHEDRA, Inorganic chemistry, 35(24), 1996, pp. 6910
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
35
Issue
24
Year of publication
1996
Database
ISI
SICI code
0020-1669(1996)35:24<6910:C-TFBW>2.0.ZU;2-I
Abstract
The first example of a dimer of corner sharing BO3 and PO4 units, BPO6 4-, occurs in the title compound. The structure is built of layers of such dimers separated by double layers of isolated PO4 tetrahedra. The cobalt atoms are 6-, 5-, and 4-coordinated by the oxygen.