Ceramic ion conducting membranes are a generic group of materials with
many potential large-scale applications in solid oxide fuel cells, ox
ygen generators and partial oxidation reactors. At present the transpo
rt and surface exchange kinetic characteristics are emphasized to maxi
mize ionic fluxes. However, as the dense membrane is often fabricated
in the form of a thick film on a supported porous structure there is a
n increasing realization that the available processing routes and ther
momechanical behaviour will also strongly influence the selection of m
aterials. Accordingly, increasing attention is now being given to the
effect of the imposed chemical potential gradient upon thermochemical
stability and structural integrity. (C) Current Chemistry Ltd