1,4-ASYMMETRIC INDUCTION FROM CHIRAL DELTA-OXYGENATED ALLYLIC TIN REAGENTS

Authors
NISHIGAICHI Y YOSHIKAWA M TAKIGAWA Y TAKUWA A
Citation
Y. Nishigaichi et al., 1,4-ASYMMETRIC INDUCTION FROM CHIRAL DELTA-OXYGENATED ALLYLIC TIN REAGENTS, Chemistry Letters, (11), 1996, pp. 961-962
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
11
Year of publication
1996
Pages
961 - 962
Database
ISI
SICI code
0366-7022(1996):11<961:1IFCDA>2.0.ZU;2-J
Abstract
A new type of asymmetric induction from allylic tin reagents is develo ped. A chiral allylic tin which has an oxygen substituent (ether or ea ter) at its delta-position successfully induces a new chirality in a 1 ,4-induction mode in the reaction with aldehydes via the transmetallat ion with SnCl4.