BULKY THIOLS AND THEIR COORDINATION-COMPOUNDS - AN IMPROVEMENT OF THEREMOVAL METHOD OF TETRAHYDROPYRANYL GROUP FROM THIOLS AND ITS APPLICATION FOR LIGAND SYNTHESES

Authors
WATANABE H OGO S YAMAMURA T
Citation
H. Watanabe et al., BULKY THIOLS AND THEIR COORDINATION-COMPOUNDS - AN IMPROVEMENT OF THEREMOVAL METHOD OF TETRAHYDROPYRANYL GROUP FROM THIOLS AND ITS APPLICATION FOR LIGAND SYNTHESES, Chemistry Letters, (11), 1996, pp. 999-1000
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
11
Year of publication
1996
Pages
999 - 1000
Database
ISI
SICI code
0366-7022(1996):11<999:BTATC->2.0.ZU;2-L
Abstract
The route for the syntheses of alkanthiols having bulky groups at the neighborhood of sulfur atoms was improved, and applied for the prepara tion of thiol ligands that mimic the cysteine containing metal binding sites in proteins. The new method developed the deprotection of tetra hydropyranyl group from alpha,alpha-diphenylalkyl 2-tetrahydropyranyl sulfides.