HOMOLYTIC DISPLACEMENT AT CARBON IN ORGANOCOBALOXIMES .9. REACTIONS OF ORGANOCOBALOXIMES WITH THIOPHENE 2-SULPHONYLCHLORIDE

Authors
GUPTA BD DAS I
Citation
Bd. Gupta et I. Das, HOMOLYTIC DISPLACEMENT AT CARBON IN ORGANOCOBALOXIMES .9. REACTIONS OF ORGANOCOBALOXIMES WITH THIOPHENE 2-SULPHONYLCHLORIDE, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 35(12), 1996, pp. 1111-1113
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical → ACNP
ISSN journal
03764710
Volume
35
Issue
12
Year of publication
1996
Pages
1111 - 1113
Database
ISI
SICI code
0376-4710(1996)35:12<1111:HDACIO>2.0.ZU;2-R
Abstract
Several allyl (both cyclic and acyclic), allenyl, hexenyl and propargy lcobaloximes react regiospecifically with thiophone-2-sulphonyl chlori de under thermal and photochemical conditions to give the correspondin g sulphones. The reaction is believed to take place by the attack of t he sulphur radical on the terminal carbon of the organocobaloxime with the displacement of cobaloxime(II).