THE NU(2) NU(4) DIAD OF PH3

Authors
AINETSCHIAN A HARING U SPIEGL G KREINER WA
Citation
A. Ainetschian et al., THE NU(2) NU(4) DIAD OF PH3, Journal of molecular spectroscopy, 181(1), 1997, pp. 99-107
Citations number
24
Categorie Soggetti
Spectroscopy,"Physics, Atomic, Molecular & Chemical
Journal title
Journal of molecular spectroscopy → ACNP
ISSN journal
00222852
Volume
181
Issue
1
Year of publication
1997
Pages
99 - 107
Database
ISI
SICI code
0022-2852(1997)181:1<99:TNNDOP>2.0.ZU;2-M
Abstract
The nu(2)/nu(4) diad of phosphine has been investigated between 920 an d 1080 cm(-1) by laser sideband spectroscopy. Using 62 observed lines and more than 250 transitions measured by other authors, including mic rowave, far infrared, and laser Stark observations, a fit was performe d, which achieved a standard deviation of 1.2 MHz. A(1)/A(2) splitting due to vibrational rotational interaction could be resolved in ten tr ansitions. (C) 1997 Academic Press, Inc.