Vm. Bujoreanu et al., ON THE FORMATION OF MANGANESE FERRITE FROM MNO2 AND FESO(4)7H(2)O AQUEOUS-SOLUTIONS THROUGH COPRECIPITATION, Thermochimica acta, 288(1-2), 1996, pp. 221-237
The formation and evolution of MnFe2O4 ferrite phase coprecipitated wi
th NaOH from MnO2 and FeSO4 . 7H(2)O in aqueous solution are discussed
, grounded on X-ray diffraction and derivatographic data, IR spectra a
nd magnetic measurements. The results concerning the nature of the ini
tial coprecipitates, their structural changes during ageing in the ori
ginal solutions at temperatures in the range 25-95 degrees C as well a
s the structure of the resulting ferritic phases are presented.