NEW CHIRAL CATALYSTS FOR THE HIGHLY ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TO ALDEHYDES

Authors
JIN MJ AHN SJ LEE KS
Citation
Mj. Jin et al., NEW CHIRAL CATALYSTS FOR THE HIGHLY ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TO ALDEHYDES, Tetrahedron letters, 37(48), 1996, pp. 8767-8770
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
48
Year of publication
1996
Pages
8767 - 8770
Database
ISI
SICI code
0040-4039(1996)37:48<8767:NCCFTH>2.0.ZU;2-B
Abstract
Optically active amino thioacetate derivatives of (+)-norephedrine wer e found to act as effective catalysts for enantioselective addition of diethylzinc to aldehydes, This reaction provided optically active sec ondary alcohols with e.e. of up to >99%. Copyright (C) 1996 Elsevier S cience Ltd