G. Buchmayer et al., PARAMAGNETIC CENTERS IN GLASSES INDUCED BY LOW-EARTH-ORBIT SPACE RADIATION, Journal of non-crystalline solids, 204(3), 1996, pp. 253-259
After having been exposed to space radiation on the experimental platf
orm Eureca (European Retrievable Carrier) for almost eleven months, di
fferent optical glasses were examined to determine radiation effects.
For the 500 km high orbit with low inclination a radiation dose of 10(
3) Cy is assumed, Using electron paramagnetic resonance (EPR) spectros
copy spectral components due to radiation effects were detected at roo
m temperature. Oxygen hole centers (OHCs) were indicated in borosilica
te glass, soda lime glass, phosphate crown glass, fluor crown glass an
d lanthanum crown glass, Ti3+ was found in borosilicate glass. All inv
estigated materials - excluding fused silica and fluoride glass - had
differing intensities of Fe3+ components caused by iron impurities in
the samples. Comparing these results to earth specimen used in a simul
ation program, specially developed in preparation for the Eureca missi
on, the same type of radiation induced defects were identified, This c
onfirms the validity of the simulation program as an appropriate tool
to predict the performance of glass materials before space missions.