MEMBRANE-BASED INTEGRATED ABSORPTION-OXIDATION REACTOR FOR DESTROYINGVOCS IN AIR

This proof-of-concept research describes a novel membrane-based, integ rated absorber-reactor operating at ambient temperature and atmospheri c pressure. It degrades volatile organic compounds (VOCs) in a gaseous stream by ozonation in an inert stagnant fluorocarbon (FC) phase havi ng a high ozone solubility. This FC phase acts as a reaction medium an d a liquid membrane. The reactor has two sets of nonporous silicone ca pillaries. The VOC-containing gas flows through one set and supplies t he VOC to the FC phase. The O-3-O-2 stream flowing through the other s upplies O-3 to the FC phase. There is also a set of microporous Teflon tubules through which water flows removing oxidation products partiti oning from the FC phase. With trichloroethylene (TCE), 60% conversion was obtained for 50 000 ppmv TCE in N-2 flowing at 30 cm(3)/min and 40 % for 18 000 ppmv flowing at 50 cm(3)/min. For 220 ppmv TCE feed, 90% conversion was obtained at 20 cm(3)/min flow rate and 60% at 60 cm(3)/ min. A conversion in excess of 97% was achieved for a toluene feed of 205 ppmv present in N-2 flowing at 11 cm(3)/min. No FC phase regenerat ion is required; it is constantly cleaned by the ozonation reactions. The materials of construction were found to hold up well under repeate d experimentation.