Mi. Gjerde et al., A NOESY NMR-STUDY OF THE INTERACTION BETWEEN SODIUM DODECYL-SULFATE AND POLY(ETHYLENE OXIDE), Journal of colloid and interface science, 183(1), 1996, pp. 285-288
The system poly(ethylene oxide) (PEG) and sodium dodecyl sulfate (SDS)
will in aqueous solution form SDS micelle-like aggregates on the poly
mer when a critical surfactant concentration (c.a.c.) is reached. The
two-dimensional nuclear Overhauser enhancement NMR (NOESY) experiment
capable of revealing spatial relationships among proximal protons has
been applied to the PEO/SDS system to study structural details of thei
r interaction. NOESY cross-peaks at sample temperatures of 283.1 and 2
98.1 K indicate proximity (<5 Angstrom) of the polymer protons and the
main part of the surfactant hydrocarbon chain. The results indicate t
hat the polymer (PEG) penetrates into the interior of the SDS micelles
. (C) 1996 Academic Press, Inc.