PREPARATION OF CHIRAL STATIONARY PHASES BASED ON ANIONICALLY POLYMERIZED S)-4-METHYL-5-PHENYL-2-(4-VINYLPHENYL)-2-OXAZOLINE

Authors
TERFLOTH G BLASCHKE G
Citation
G. Terfloth et G. Blaschke, PREPARATION OF CHIRAL STATIONARY PHASES BASED ON ANIONICALLY POLYMERIZED S)-4-METHYL-5-PHENYL-2-(4-VINYLPHENYL)-2-OXAZOLINE, Macromolecular chemistry and physics, 195(12), 1994, pp. 3863-3868
Citations number
10
Categorie Soggetti
Polymer Sciences
Journal title
Macromolecular chemistry and physics → ACNP
ISSN journal
10221352
Volume
195
Issue
12
Year of publication
1994
Pages
3863 - 3868
Database
ISI
SICI code
1022-1352(1994)195:12<3863:POCSPB>2.0.ZU;2-V
Abstract
S)-4-methyl-5-phenyl-2-(4-vinylphenyl)-2-oxazoline (1) was prepared. T he anionic polymerisation of 1 was initiated in toluene with butyllith ium (BuLi) at -78-degrees-C to afford poly(1) of narrow molecular weig ht distribution. The resulting poly(1) was immobilised on modified sil ica gel to give chiral stationary phases for the separation of racemic compounds.