FROM SUGARS TO CARBOCYCLES .4. EXCLUSIVE 7-MEMBERED RING FORMATION FROM D-GLUCOSE

Authors
KROHN K GRINGARD S BORNER G
Citation
K. Krohn et al., FROM SUGARS TO CARBOCYCLES .4. EXCLUSIVE 7-MEMBERED RING FORMATION FROM D-GLUCOSE, Tetrahedron : asymmetry, 5(12), 1994, pp. 2485-2492
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
5
Issue
12
Year of publication
1994
Pages
2485 - 2492
Database
ISI
SICI code
0957-4166(1994)5:12<2485:FSTC.E>2.0.ZU;2-0
Abstract
An example of the 1,3-dithiane methodology of carbocyclization of suga rs leading selectively to a seven-membered ring 16 is presented. The s electivity is discussed in terms of steric hindrance of the respective six-membered transition states.