THE ROLE OF CHLORINE IN METHANE COUPLING PEROVSKITE CATALYSTS

Authors
TEYMOURI M PETIT C HILAIRE L BAGHERZADEH E KIENNEMANN A
Citation
M. Teymouri et al., THE ROLE OF CHLORINE IN METHANE COUPLING PEROVSKITE CATALYSTS, Catalysis today, 21(2-3), 1994, pp. 377-385
Citations number
14
Categorie Soggetti
Engineering, Chemical","Chemistry Applied","Chemistry Physical
Journal title
Catalysis today → ACNP
ISSN journal
09205861
Volume
21
Issue
2-3
Year of publication
1994
Pages
377 - 385
Database
ISI
SICI code
0920-5861(1994)21:2-3<377:TROCIM>2.0.ZU;2-L
Abstract
ABO(3) perovskite (A = Ca, Sr, Ba; B = Ti, Zr) has been prepared by a sol-gel method from oxygenated (I) or chlorinated (II) precursors. The difference in C-2-hydrocarbon selectivity depending on the preparatio n mode is ascribed to the presence of chlorine. To understand the effe ct of chlorine, the various catalysts have been characterized by XRD, BET, O-2 temperature programmed desorption. Addition of organic chlori nated compounds as probe molecules have been studied and compared on c atalysts I and II.