MODELING AND SIMULATION OF HETEROGENEOUS OXIDATION OF METHANE ON A PLATINUM FOIL

Citation
O. Deutschmann et al., MODELING AND SIMULATION OF HETEROGENEOUS OXIDATION OF METHANE ON A PLATINUM FOIL, Catalysis today, 21(2-3), 1994, pp. 461-470
Citations number
32
Categorie Soggetti
Engineering, Chemical","Chemistry Applied","Chemistry Physical
Journal title
ISSN journal
09205861
Volume
21
Issue
2-3
Year of publication
1994
Pages
461 - 470
Database
ISI
SICI code
0920-5861(1994)21:2-3<461:MASOHO>2.0.ZU;2-5
Abstract
The heterogeneous oxidation of methane-air mixtures in a stagnation po int flow onto a platinum foil is investigated numerically and results are compared with experiments. The analysis includes a detailed reacti on mechanism in the gas phase as well as on the surface. The heterogen eous ignition occurring around 600 degrees C, extinction, and autother mal behaviour are interpreted in terms of elementary steps at the gas- surface interface.